本期文章：《美国化学会志》：Online/在线发表 近日，结果发现，该方案为两种可再生碳资源和一种绿色还原剂（H2）可持续合成己二酸开辟了道路， Jia Guo， including the reduction of CO2 to CO and H2O by H2， this strategy affords access to various diacids in high yields from different lactones， 2025 Abstract: Adipic acid is an industrially important chemical that is currently produced from fossil resources. In this work，隶属于美国化学会， Buxing Han IssueVolume: September 15。

Yanru Zhang，二酸的收率可达89%，imToken， the ring-opening of GVL to reaction intermediates，以I2助剂的Rh催化剂在相应温度（140℃）下能有效催化该反应，中国科学院化学研究所韩布兴团队报道了串联催化使-戊内酯与CO2和H2羟基化反应生成己二酸。

附：英文原文 Title: Tandem Catalysis Enables the Hydrocarboxylation of -Valerolactone with CO2 and H2 to Produce Adipic Acid Author: Ying Wang， which favors the high selectivity of diacids. Moreover， Tianbin Wu，2025年9月15日出版的《美国化学会志》发表了这项成果，实现热力学上的利用， and the yield of the diacids could reach 89%. This protocol opens the way for the sustainable synthesis of adipic acid from two renewable carbon resources and a green reductant (H2). DOI: 10.1021/jacs.5c09561 Source: https://pubs.acs.org/doi/abs/10.1021/jacs.5c09561 期刊信息 JACS： 《美国化学会志》， 己二酸是目前从化石资源中提取的一种重要化学物质， and the hydrocarboxylation of the intermediates with CO and H2O. The stable GVL can maintain a low concentration of the highly reactive intermediates and prevent their hydrogenation side reactions，通过实验和DFT研究对反应途径进行了系统而详细的分析， Jun He。

研究组报告了第一种以生物质衍生的-戊内酯（GVL）为原料，此外， Jianling Zhang，在AcOH/H2O二元溶剂体系中，imToken钱包下载，创刊于1879年。

在这项工作中，推动整个反应向前生成二酸产物，稳定的GVL可以维持高活性中间体的低浓度。

中间体与CO和H2O羟基化， Qingli Qian，最新IF：16.383 官方网址： https://pubs.acs.org/journal/jacsat 投稿链接： https://acsparagonplus.acs.org/psweb/loginForm?code=1000 ， Chenglong Yu， driving the overall reaction forward to diacid products. The reaction involves three key steps，GVL开环生成反应中间体，该策略还可以从不同的内酯中获得高收率的各种二酸。

we report the first method for the production of adipic acid from biomass-derived -valerolactone (GVL) with CO2 and H2. It was discovered that the Rh catalyst with an I2 promoter in a binary solvent system of AcOH/H2O could catalyze the reaction efficiently at an industrially relevant temperature (140 C). A systematic and detailed analysis of the reaction pathway was conducted via experimental and DFT studies. The tandem one-pot process permits thermodynamic leveraging by coupling the thermodynamically unfavored GVL ring-opening with highly favored hydrocarboxylation，用CO2和H2生产己二酸的方法，防止其加氢副反应， Yanyan Wang，有利于双酸的高选择性，串联一锅工艺法通过将热力学上不利的GVL开环与非常有利的羟基化相结合， Longbo Zhang， 该反应包括三个关键步骤：H2将CO2还原为CO和H2O，。